occurs in all cereal grains, but barley produces by far the most diastase enzymes and hence the most maltose sugar.) At a time when few other sources of sugar were available, the sweetness of this "malted" grain would have been highly valued, prompting the development of deliberate malting techniques, in which the grain was first soaked and then dried.
The second discovery was even more momentous. Gruel that was left sitting around for a couple of days underwent a mysterious transformation, particularly if it had been made with malted grain: It became slightly fizzy and pleasantly intoxicating, as the action of wild yeasts from the air fermented the sugar in the gruel into alcohol. The gruel, in short, turned into beer. Even so, beer was not necessarily the first form of alcohol to pass human lips. At the time of beer's discovery, alcohol from the accidental fermentation of fruit juice (to make wine) or water and honey (to make mead) would have occurred naturally in small quantities as people tried to store fruit or honey. But fruit is seasonal and perishes easily, wild honey was only available in limited quantities, and neither wine nor mead could be stored for very long without pottery, which did not emerge until around 6000 BCE. Beer, on the other hand, could be made from cereal crops, which were abundant and could be easily stored, allowing beer to be made reliably, and in quantity, when needed. Long before pottery was available, it could have been brewed in pitch-lined baskets, leather bags or animal stomachs, hollowed-out trees, large shells, or stone vessels. Shells were used for cooking as recently as the nineteenth century in the Amazon basin, and Sahti, a traditional beer made in Finland, is still brewed in hollowed-out trees today.
Once the crucial discovery of beer had been made, its quality was improved through trial and error. The more malted grain there is in the original gruel, for example, and the longer it is left to ferment, the stronger the beer. More malt means more sugar, and a longer fermentation means more of the sugar is turned into alcohol. Thoroughly cooking the gruel also contributes to the beer's strength. The malting process converts only around 15 percent of the starch found in barley grains into sugar, but when malted barley is mixed with water and brought to the boil, other starch-converting enzymes, which become active at higher temperatures, turn more of the starch into sugar, so there is more sugar for the yeast to transform into alcohol.
Ancient brewers also noticed that using the same container repeatedly for brewing produced more reliable results. Later historical records from Egypt and Mesopotamia show that brewers always carried their own "mash tubs" around with them, and one Mesopotamian myth refers to "containers which make the beer good." Repeated use of the same mash tub promoted successful fermentation because yeast cultures took up residence in the container's cracks and crevices, so that there was no need to rely on the more capricious wild yeast. Finally, adding berries, honey, spices, herbs, and other flavorings to the gruel altered the taste of the resulting beer in various ways. Over the next few thousand years, people discovered how to make a variety of beers of different strengths and flavors for different occasions.
Later Egyptian records mention at least seventeen kinds of beer, some of them referred to in poetic terms that sound, to modern ears, almost like advertising slogans: Different beers were known as "the beautiful and good," "the heavenly," "the joy-bringer," "the addition to the meal," "the plentiful," "the fermented." Beers used in religious ceremonies also had special names. Similarly, early written references to beer from Mesopotamia, in the third millennium BCE, list over twenty different kinds, including fresh beer, dark beer, fresh-dark beer, strong beer, red-brown beer, light beer, and pressed beer. Red-brown beer was a dark beer made using extra